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B(C 6 F 5 ) 3 ‐Catalyzed E ‐selective isomerization of alkenes

Kustiana, Betty A., Elsherbeni, Salma A., Linford‐Wood, Thomas G., Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831, Grayson, Matthew N. and Morrill, Louis C. ORCID: https://orcid.org/0000-0002-6453-7531 2022. B(C 6 F 5 ) 3 ‐Catalyzed E ‐selective isomerization of alkenes. Chemistry - A European Journal , e202202454. 10.1002/chem.202202454

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License URL: http://creativecommons.org/licenses/by/4.0/
License Start date: 9 August 2022

Abstract

Abstract: Herein, we report the B(C6F5)3‐catalyzed E‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Additional Information: License information from Publisher: LICENSE 1: URL: http://creativecommons.org/licenses/by/4.0/
Publisher: Wiley
ISSN: 0947-6539
Funders: EPSRC
Date of First Compliant Deposit: 2 September 2022
Date of Acceptance: 9 August 2022
Last Modified: 07 Jun 2023 17:19
URI: https://orca.cardiff.ac.uk/id/eprint/152308

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