Knobby surfaced, mesoporous, single-phase GIS-NaP1 zeolite microsphere synthesis and characterization for H2 gas adsorption

Sharma, Pankaj ORCID: https://orcid.org/0000-0003-2319-260X, Yeo, Jeong-gu, Han, Moon Hee and Cho, Churl Hee 2013. Knobby surfaced, mesoporous, single-phase GIS-NaP1 zeolite microsphere synthesis and characterization for H2 gas adsorption. Journal of Materials Chemistry A: materials for energy and sustainability 1 (7) , pp. 2602-2612. 10.1039/c2ta01311h

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Abstract

Single-phase GIS-NaP1 zeolite particles were hydrothermally synthesized from inorganic precursor solutions. The as-synthesized GIS-NaP1 zeolite particles have spherical morphology similar to Myrica rubra fruit. These knobby surfaced GIS-NaP1 zeolite spheres of size 0.8 to 1.8 μm were composed of crystalline nanoparticles with a crystallite size of around 27.4 nm. The diffraction, spectroscopic and scanning analysis results evidently show high phase-purity of as-synthesized GIS-NaP1 zeolite particles of uniform size, shape and morphology. Textural characterization of as-synthesized GIS-NaP1 zeolite predicts the mesoporous character. The adsorption performances of H2 and CO2 on phase-pure GIS-NaP1 zeolite were investigated at 303 K and pressure ranging from 0 to 1 bar. Magnificently, as-synthesized GIS-NaP1 zeolite shows good adsorption potential for H2 (2.29 mmol g−1) compared to CO2 (0.03 mmol g−1). The high adsorption selectivity (76.33) to H2 over CO2 may be due to the small zeolitic pore diameter and high Si/Al ratio.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Royal Society of Chemistry
ISSN:	2050-7488
Date of Acceptance:	12 December 2012
Last Modified:	16 Nov 2022 16:45
URI:	https://orca.cardiff.ac.uk/id/eprint/153534

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