Pinheiro, Lucimar, Gonzaga De Oliveira, Luciana and Marsaioli, Anita J. 2009. Assessing the absolute configuration of (7S,8R)-(−)-epoxyjasmone. Journal of Molecular Catalysis B: Enzymatic 60 (3-4) , pp. 133-137. 10.1016/j.molcatb.2009.04.010 |
Official URL: http://dx.doi.org/10.1016/j.molcatb.2009.04.010
Abstract
The absolute configuration of cis-epoxyjasmone (−)-2, isolated from Trichosporum cutaneum CCT 1903 whole cells, has been unambiguously established as (7S,8R), [α]D20 −29.0° (c 1.3, CHCl3), by a new two step method, using a regioselective epoxide opening as the key step followed by Mosher acid derivatization.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Elsevier |
ISSN: | 1381-1177 |
Date of Acceptance: | 22 April 2009 |
Last Modified: | 14 Nov 2022 16:05 |
URI: | https://orca.cardiff.ac.uk/id/eprint/153695 |
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