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Assessing the absolute configuration of (7S,8R)-(−)-epoxyjasmone

Pinheiro, Lucimar, Gonzaga De Oliveira, Luciana and Marsaioli, Anita J. 2009. Assessing the absolute configuration of (7S,8R)-(−)-epoxyjasmone. Journal of Molecular Catalysis B: Enzymatic 60 (3-4) , pp. 133-137. 10.1016/j.molcatb.2009.04.010

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The absolute configuration of cis-epoxyjasmone (−)-2, isolated from Trichosporum cutaneum CCT 1903 whole cells, has been unambiguously established as (7S,8R), [α]D20 −29.0° (c 1.3, CHCl3), by a new two step method, using a regioselective epoxide opening as the key step followed by Mosher acid derivatization.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Elsevier
ISSN: 1381-1177
Date of Acceptance: 22 April 2009
Last Modified: 14 Nov 2022 16:05

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