Cyclometallated nitrogen heterocycles

Slater, J.W. and Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021 2003. Cyclometallated nitrogen heterocycles. Journal of Organometallic Chemistry 688 (1-2) , pp. 112-120. 10.1016/j.jorganchem.2003.08.038

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Abstract

The cyclometallation of four different classes of nitrogen heterocycle (pyridazine, tetrazines, pyrazines and pyrimidines) by palladium and platinum has been studied. Pyridazines readily form singly and doubly cyclometallated compounds, whilst pyrazines only metallate once. Both tetrazines and pyrimidines readily metallate once and doubly metallated species have been identified in solution. The use of trans-cyclometallating reagents based on benzylamine and Schiff's base ligands was also studied: considerable promise was shown by a benzylamine compound. The multiple cyclometallation of 4 different classes of nitrogen heterocycle by palladium and platinum has been studied.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Elsevier
ISSN:	0022-328X
Last Modified:	13 Apr 2023 13:30
URI:	https://orca.cardiff.ac.uk/id/eprint/155215

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