Metal-free C–S coupling of thiols and disulfides

Pramanik, Milan, Choudhuri, Khokan and Mal, Prasenjit 2020. Metal-free C–S coupling of thiols and disulfides. Organic and Biomolecular Chemistry 18 (43) , pp. 8771-8792. 10.1039/D0OB01741H

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Abstract

In organic synthesis, transition-metal and photoredox-catalysis-based reaction systems are emerging trends for the construction of C–S bonds. Many review articles have recently appeared in this field; however, we present herein an overview of metal-free C–S coupling reactions using thiols or disulfides as sulfur surrogates. The oxidants we have considered include peroxides, tert-butyl nitrite (TBN), DDQ, iodine reagents, and molecular oxygen. In addition, selective electrochemical oxidative transformations are also covered with mechanistic details.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-0520
Date of First Compliant Deposit:	11 January 2023
Date of Acceptance:	2 October 2020
Last Modified:	11 Jan 2023 12:43
URI:	https://orca.cardiff.ac.uk/id/eprint/155243

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