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Metal-free C–S coupling of thiols and disulfides

Pramanik, Milan, Choudhuri, Khokan and Mal, Prasenjit 2020. Metal-free C–S coupling of thiols and disulfides. Organic and Biomolecular Chemistry 18 (43) , pp. 8771-8792. 10.1039/D0OB01741H

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In organic synthesis, transition-metal and photoredox-catalysis-based reaction systems are emerging trends for the construction of C–S bonds. Many review articles have recently appeared in this field; however, we present herein an overview of metal-free C–S coupling reactions using thiols or disulfides as sulfur surrogates. The oxidants we have considered include peroxides, tert-butyl nitrite (TBN), DDQ, iodine reagents, and molecular oxygen. In addition, selective electrochemical oxidative transformations are also covered with mechanistic details.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-0520
Date of First Compliant Deposit: 11 January 2023
Date of Acceptance: 2 October 2020
Last Modified: 11 Jan 2023 12:43

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