Direct c-s bond functionalization of benzyl mercaptan

Choudhuri, Khokan, Pramanik, Milan and Mal, Prasenjit 2020. Direct c-s bond functionalization of benzyl mercaptan. European Journal of Organic Chemistry 2020 (25) , pp. 3906-3913. 10.1002/ejoc.202000521

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Abstract

Cleavage of a C–S bond of benzyl mercaptan led to formation of a new C–C bond during (Z)-selective alkenylation of nitriles using 1,10-phenanthroline as organocatalyst and tBuOK as a base. Furthermore, we have shown that the cascaded functionalization of benzylic C–S and aryl–halide bonds could be done in one pot. 1H NMR study and kinetic experiments also helped to establish the mechanism of the reaction.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1434-193X
Date of First Compliant Deposit:	10 January 2023
Date of Acceptance:	27 May 2020
Last Modified:	11 Jan 2023 12:48
URI:	https://orca.cardiff.ac.uk/id/eprint/155246

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