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Sulfur...oxygen interaction-controlled (Z)-selective anti-Markovnikov vinyl sulfides

Pramanik, Milan, Mathuri, Ashis and Mal, Prasenjit 2021. Sulfur...oxygen interaction-controlled (Z)-selective anti-Markovnikov vinyl sulfides. Chemical Communications 57 (46) , pp. 5698-5701. 10.1039/D1CC01257F

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The sulfur oxygen (S⋯O) interaction was used herein to obtain (Z)-selective anti-Markovnikov vinyl sulfides from the addition of thiyl radicals to terminal alkynes. DFT calculations predicted that S⋯O interaction originated from the delocalization of the lone-pair of the carbonyl oxygen to the adjacent σ* orbital of the S atom of C–S.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of Acceptance: 5 May 2021
Last Modified: 24 Jan 2023 10:30

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