Boruah, Tribani, Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667
2023.
Isodesmic metathesis chemistry: A novel way to recycle P(V).
Chem Catalysis
3
(8)
, 100731.
10.1016/j.checat.2023.100731
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Official URL: http://dx.doi.org/10.1016/j.checat.2023.100731
Abstract
Since the P=O bond is thermodynamically inert, reducing phosphine oxides to phosphines is notoriously challenging. This preview highlights the recent findings of Xue et al., who describe, through thermodynamic and mechanistic investigation, a novel synthetic pathway for reducing phosphine oxide by employing isodesmic reactions without stoichiometric activators.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry Cardiff Catalysis Institute (CCI) |
Publisher: | Cell Press |
ISSN: | 2667-1093 |
Date of First Compliant Deposit: | 23 August 2023 |
Date of Acceptance: | 31 July 2023 |
Last Modified: | 07 Nov 2023 16:30 |
URI: | https://orca.cardiff.ac.uk/id/eprint/162003 |
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