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Reactivity of a series of triaryl borates, B(OAr x) 3, in hydroboration catalysis

Sokolnicki, Tomasz, Alharbi, Mashael M., van Ingen, Yara, Rahim, Shahnaz, Pramanik, Milan, Roldan Martinez, Alberto ORCID:, Walkowiak, Jędrzej and Melen, Rebecca L. ORCID: 2023. Reactivity of a series of triaryl borates, B(OAr x) 3, in hydroboration catalysis. Dalton Transactions 52 (44) , pp. 16118-16122. 10.1039/d3dt03333c

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In this paper, we compare the reactivity of a series of triaryl borates B(OArx)3 as catalysts for the hydroboration of alkenes and alkynes. It was observed that commercially available B(OPh)3 performed the poorest, whereas catalysts with o-F atoms appeared to perform much better.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Additional Information: License information from Publisher: LICENSE 1: URL:, Start Date: 2023-10-20
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Date of First Compliant Deposit: 31 October 2023
Date of Acceptance: 15 October 2023
Last Modified: 07 Dec 2023 14:15

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