Lewis, Richard J.
2026.
Confined Pd clusters for enhanced direct ammoximation using H2 and O2.
Chem Catalysis
6
(3)
, 101667.
10.1016/j.checat.2026.101667
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Official URL: https://doi.org/10.1016/j.checat.2026.101667
Abstract
In Nature Catalysis, Wu and co-workers report a Ti-mordenite-confined, ultra-low-loaded Pd catalyst that advances in situ cyclohexanone ammoximation beyond proof of concept to deliver 99% oxime selectivity over 4,000 h of stable operation. By stabilizing sub-nanometric Pd clusters adjacent to Ti sites, the work establishes a highly efficient platform with the potential to reshape industrial oxidation.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI) |
| Additional Information: | RRS policy applied |
| Publisher: | Cell Press |
| ISSN: | 2667-1093 |
| Date of First Compliant Deposit: | 30 March 2026 |
| Date of Acceptance: | 12 February 2026 |
| Last Modified: | 03 Aug 2026 14:00 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/186066 |
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