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Influence of water-to-binder ratio on the properties and hydration of solid waste-based ultra-high performance concrete

Mu, Xinli, Zhang, Siqi, Xu, Dong, Li, Ying, Ni, Wen and Jin, Fei ORCID: https://orcid.org/0000-0003-0899-7063 2026. Influence of water-to-binder ratio on the properties and hydration of solid waste-based ultra-high performance concrete. Construction and Building Materials 537 , 147084. 10.1016/j.conbuildmat.2026.147084

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Abstract

Concrete production is associated with significant CO2 emissions and natural resource depletion. In this study, a fully solid waste-based ultra-high performance concrete (SW-UHPC) formulation was developed. Refining slag, hot stifle steel slag, blast furnace slag and desulfurised gypsum were used as cementitious materials, while roller steel slag sand was used as aggregate. The effects of the water-to-binder (w/b) ratio (ranging from 0.18 to 0.22) on the workability, mechanical properties, hydration and microstructure of SW-UHPC were systematically investigated. At lower w/b ratios, the restricted water availability limited the overall degree of hydration but concurrently produced a denser microstructure: unhydrated solid-waste particles acted as load-bearing micro-aggregates and the hydration products formed filled the interparticle pores, yielding a maximum 28-day compressive strength of 113.11 MPa at w/b = 0.18. At higher w/b ratios, enhanced hydration increased the formation of ettringite and C-(A)-S-H gel but also elevated matrix porosity, progressively reducing compressive strength. Flexural strength exhibited a non-monotonic response, reaching a peak of 37.22 MPa at w/b = 0.20, reflecting an optimal balance between matrix compactness and workability-dependent fibre dispersion. These results demonstrate that the w/b ratio governs SW-UHPC mechanical performance by regulating hydration continuity, microstructural densification and rheology-dependent fibre dispersion, rather than by maximising hydration degree alone. The use of these solid waste-derived constituents enabled a reduction of > 50% raw-material-related carbon emissions and material cost compared with conventional UHPC, while achieving effective valorisation of multiple industrial by-products.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Schools > Engineering
Additional Information: RRS applied
Publisher: Elsevier
ISSN: 0950-0618
Date of First Compliant Deposit: 10 July 2026
Date of Acceptance: 13 June 2026
Last Modified: 10 Jul 2026 09:30
URI: https://orca.cardiff.ac.uk/id/eprint/188043

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