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Reactions of alkylidenepyrrolidines with alpha-chlorooximes and alpha-chlorohydrazones

Altug, Cevher, Dürüst, Yasar and Elliott, Mark Christopher 2009. Reactions of alkylidenepyrrolidines with alpha-chlorooximes and alpha-chlorohydrazones. Tetrahedron Letters 50 (52) , pp. 7392-7394. 10.1016/j.tetlet.2009.10.086

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The reactions of alkylidenepyrrolidines with α-chlorooximes give isoxazoles via an acylation reaction followed by ring isomerisation. In contrast, and in line with a previous report, the corresponding α-chlorohydrazones give the simple acylation products, although in one instance a cycloadduct was also obtained.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Pergamon-Elsevier Science Ltd
ISSN: 0040-4039
Last Modified: 04 Jun 2017 03:38

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