Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5

Hammond, Ceri ORCID: https://orcid.org/0000-0002-9168-7674, Forde, Michael M., Ab Rahim, Mohd Hasbi, Thetford, Adam, He, Qian ORCID: https://orcid.org/0000-0003-4891-3581, Jenkins, Robert Leyshon, Dimitratos, Nikolaos ORCID: https://orcid.org/0000-0002-6620-4335, Lopez-Sanchez, Jose Antonio, Dummer, Nicholas ORCID: https://orcid.org/0000-0002-0946-6304, Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879, Carley, Albert Frederick, Taylor, Stuart H. ORCID: https://orcid.org/0000-0002-1933-4874, Willock, David James ORCID: https://orcid.org/0000-0002-8893-1090, Stangland, Eric E., Kang, Joo, Hagen, Henk, Kiely, Christopher John ORCID: https://orcid.org/0000-0001-5412-0970 and Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560 2012. Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angewandte Chemie - International Edition 51 (21) , pp. 5129-5133. 10.1002/anie.201108706

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Abstract

Iron copper zeolite (Fe-Cu-ZSM-5) with aqueous hydrogen peroxide is active for the selective oxidation of methane to methanol. Iron is involved in the activation of the carbon–hydrogen bond, while copper allows methanol to form as the major product. The catalyst is stable, re-usable and activates methane giving >90 % methanol selectivity and 10 % conversion in a closed catalytic cycle (see scheme).

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Advanced Research Computing @ Cardiff (ARCCA) Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Copper; Heterogeneous catalysts; Iron; Methane; Zeolite
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	16 Oct 2024 10:18
URI:	https://orca.cardiff.ac.uk/id/eprint/30288

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