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Asymmetric hetero-Diels-Alder reactions. Reactions of oxazolo[3,2-c]pyrimidines

Elliott, Mark Christopher, Kruiswijk, Elbertus and Willock, David James 2001. Asymmetric hetero-Diels-Alder reactions. Reactions of oxazolo[3,2-c]pyrimidines. Tetrahedron 57 (51) , pp. 10139-10146. 10.1016/S0040-4020(01)01032-8

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Diastereomerically pure oxazolo[3,2-c]pyrimidines can be readily prepared by the reaction of alkenyloxazolines with isocyanates. The mechanism of this transformation has been investigated computationally. These compounds undergo epimerisation upon prolonged heating, a reaction which is consistent with the proposed stepwise mechanism. Hydrolysis reactions of these compounds have been investigated.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: asymmetric reactions; Biginelli reactions; pyrimidones; oxazolines
Publisher: Elsevier
ISSN: 0040-4020
Last Modified: 09 Apr 2022 09:30

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