Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties

Herrera, Juan-Manuel, Ward, Michael D., Adams, Harry, Pope, Simon J. A. ORCID: https://orcid.org/0000-0001-9110-9711 and Faulkner, Stephen 2006. Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: photophysical and structural properties. Chemical Communications 2006 (17) , pp. 1851-1853. 10.1039/b601876a

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Abstract

The complexes [Ru(CN)4(HAT)]2−, [{Ru(CN)4}2(μ2-HAT)]4− and [{Ru(CN)4}3(μ3-HAT)]6− (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6− forms a high-dimensionality cyanide-bridged coordination network with Nd(III), in which Ru → Nd energy transfer results in sensitised near-IR luminescence.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	1359-7345
Last Modified:	21 Oct 2022 10:53
URI:	https://orca.cardiff.ac.uk/id/eprint/41630

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