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Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity

Newman, Paul David ORCID:, Cavell, Kingsley John and Kariuki, Benson ORCID: 2012. Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity. Chemical Communications 48 (52) , pp. 6511-6513. 10.1039/c2cc33036a

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An unusual example of diastereoselectivity has been observed in Cu(κ3-P,C,P′-1)X complexes where 1 is an asymmetric tridentate ligand containing a bicyclic NHC framework and X is a halide. When X is Cl−, the SCu isomer is formed selectively whereas when X = I− the RCu diastereomer is preferred.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Last Modified: 24 Oct 2022 11:10

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