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The synthesis and structure of terpyridine-N-oxide complexes of copper(II) perchlorate

Amoroso, Angelo James ORCID: https://orcid.org/0000-0002-7601-5482, Burrows, M. W., Coles, S. J., Haigh, R., Farley, R. D., Hursthouse, M. B., Jones, M., Malik, K. M. A. and Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879 2008. The synthesis and structure of terpyridine-N-oxide complexes of copper(II) perchlorate. Dalton Transactions (4) , pp. 506-513. 10.1039/b713444d

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Abstract

The co-ordination of a series of terpyridine-N-oxide ligands to the Cu(II) ion is reported. Addition of two equivalents of ligand results in the formation of the expected 2 : 1 six co-ordinate product, while the addition of one equivalent of ligand allows the isolation of 1 : 1 species if the ligand has a meridonal binding mode. The five complexes isolated were characterised in the solid state by X-ray crystallography while they are studied in solution using EPR, UV-vis spectroscopy and IR spectroscopy.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC
ISSN: 1477-9226
Last Modified: 17 Oct 2022 09:49
URI: https://orca.cardiff.ac.uk/id/eprint/5843

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