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7.29 oxidative functionalization with hypervalent halides

Singh, Fateh Veer and Wirth, Thomas 2014. 7.29 oxidative functionalization with hypervalent halides. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 7 , pp. 880-933. 10.1016/B978-0-08-097742-3.00735-7

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In past two decades, hypervalent iodine chemistry has developed as an important tool in synthetic and natural product chemistry. Hypervalent iodine reagents have been applied to a variety of reactions such as oxidations, oxidative cyclizations, and rearrangements. Many synthetic transformations can also be achieved by using these reagents as catalysts. Recently, chiral hypervalent iodine reagents have been used for synthetically valuable stereoselective transformations. This chapter describes oxidative functionalizations with hypervalent iodine(III) and (V) reagents as well as hypervalent bromine compounds.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Hypervalent bromine; Hypervalent iodine; Oxidations; Polymer-supported reagents; Rearrangements.
Additional Information: Electronic book
Publisher: Elsevier
ISBN: 9780080977423
Last Modified: 18 Feb 2019 13:35

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