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Dimorphism in a 2,2,2-terpyridyl compound

Gillard, Robert D., Sengul, Abdurrahman and Oldroyd, Anthony 2001. Dimorphism in a 2,2,2-terpyridyl compound. Transition Metal Chemistry 26 (3) , pp. 339-344. 10.1023/A:1007120731989

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Chloro-(2,2′,2″-terpyridine)platinum(II) chloride dihydrate, [Pt(terpy)Cl]Cl · 2H2O, crystallizes from aqueous EtOH (1:1) as a yellow dimorph, but from dilute (1 M) HCl as its less stable red dimorph. X-ray powder photography shows that, above 100 °C, the red form converts into the yellow form.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Earth and Environmental Sciences
Subjects: Q Science > QD Chemistry
Publisher: Springer
Last Modified: 04 Jun 2017 08:02

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