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Enantioselective oxidative rearrangements with chiral hypervalent iodine reagents

Brown, Michael, Kumar, Ravi, Rehbein, Julia and Wirth, Thomas 2016. Enantioselective oxidative rearrangements with chiral hypervalent iodine reagents. Chemistry - a European Journal 22 (12) , pp. 4030-4035. 10.1002/chem.201504844

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A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α-arylated ketones without the use of transition metals from readily accessible alkenes.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: WileyBlackwell
ISSN: 0947-6539
Funders: EPSRC
Date of First Compliant Deposit: 30 March 2016
Date of Acceptance: 21 December 2015
Last Modified: 24 Apr 2018 22:17

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