Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Preparation and characterisation of nanostructured bulk Bi2Te3 thermoelectric materials using ultrasound milling

Marques-Garcia, Lourdes 2016. Preparation and characterisation of nanostructured bulk Bi2Te3 thermoelectric materials using ultrasound milling. PhD Thesis, Cardiff University.
Item availability restricted.

[thumbnail of 2016Marquez-GarciaLPhD.pdf]
PDF - Accepted Post-Print Version
Download (10MB) | Preview
[thumbnail of Marques-GarciaL.pdf] PDF - Supplemental Material
Restricted to Repository staff only

Download (1MB)


Thermoelectric materials have been intensively investigated during the last years for energy harvesting applications. The main drawback of this technology is the low efficiency of the current materials. Significant advances in this respect have been recently achieved by nanostructuring, to mainly reduce the thermal conductivity. In this approach a bulk sample is milled into a nanostructured powder that is then compacted to form a nanobulk sample. The main objective of this thesis is to explore and introduce a new technique, ultrasound milling, based on the crushing of bulk samples by means of ultrasound effects taking place in a liquid medium, for the preparation of nanostructured bulk materials. Bismuth telluride alloys are the industrial standard in thermoelectrics and has been chosen as the material to perform this investigation. The most suitable conditions for the preparation of the nanostructured powders by the ultrasound milling technique have been identified. The optimised powders were used to prepare compacted nanobulk samples. The thermoelectric properties of these samples were finally characterised at room temperature and their performance related to their microstructure. Extraordinarily low thermal conductivity was obtained for both n- and p-type samples prepared (0.5 and 0.35 W/Km respectively), which are within the lowest reported values for any thermoelectric alloy. This reduction was accompanied with a significant decrease in electrical conductivity which led to a non-significant improvement in the figure of merit (Z). However, high ZT values (1 and 1.4 for n- and p-type bismuth telluride respectively) were identified in non-treated samples after a very simple grinding process which was employed as pre-treatment. The figure of merit of these two materials prepared by this simple methodology is close to the best reported values for Bi2Te3. Our results identify ultrasound milling and the simple crushing method as promising tools for the fabrication of nanostructured bulk thermoelectric materials.

Item Type: Thesis (PhD)
Date Type: Completion
Status: Unpublished
Schools: Engineering
Subjects: T Technology > TK Electrical engineering. Electronics Nuclear engineering
Uncontrolled Keywords: Bismuth Telluride; Nanostructured Bulk Materials; Ultrasound Milling.
Date of First Compliant Deposit: 4 August 2016
Last Modified: 18 Aug 2021 13:19

Actions (repository staff only)

Edit Item Edit Item


Downloads per month over past year

View more statistics