Wood protection properties of quaternary ammonium spiroborate esters derived from alkyl tartrates

Carr, Jenny M., Duggan, Peter James, Humphrey, David G., Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595 and Tyndall, Edward M. 2011. Wood protection properties of quaternary ammonium spiroborate esters derived from alkyl tartrates. Australian Journal of Chemistry 64 (4) , pp. 495-502. 10.1071/CH11022

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Abstract

Four new tetra-n-butylammonium spiroborates derived from dimethyl, diethyl, di-iso-propyl and di-n-butyl esters of l-tartaric acid have been prepared and their potential as environmentally benign wood protectants investigated. These compounds showed good activity in a no-choice cellulose paper bioassay with Coptotermes acinaciformis termites. The hydrolytic stability of these spiroborates is not high relative to other spiroborates, yet the tetra-n-butylammonium spiroborate derived from di-iso-propyl-l-tartrate showed remarkable permanence in timber in a demanding leaching test.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	CSIRO Publishing
ISSN:	0004-9425
Last Modified:	18 Oct 2022 12:24
URI:	https://orca.cardiff.ac.uk/id/eprint/9683

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