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Highly productive CO2 hydrogenation to methanol – a tandem catalytic approach via amide intermediates

Everett, M. and Wass, D. F. 2017. Highly productive CO2 hydrogenation to methanol – a tandem catalytic approach via amide intermediates. Chemical Communications 53 (68) , pp. 9502-9504. 10.1039/C7CC04613H

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Abstract

A new system for CO2 reduction to methanol has been demonstrated using homogeneous ruthenium catalysts with a range of amine auxiliaries. Modification of this amine has a profound effect on the yield and selectivity of the reaction. A TON of 8900 and TOF of 4500 h−1 is achieved using a [RuCl2(Ph2PCH2CH2NHMe)2] catalyst with a diisopropylamine auxiliary.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 22 October 2018
Date of Acceptance: 23 June 2017
Last Modified: 24 Nov 2020 19:11
URI: http://orca.cardiff.ac.uk/id/eprint/116083

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