Highly productive CO2 hydrogenation to methanol – a tandem catalytic approach via amide intermediates

Everett, M. and Wass, D. F. ORCID: https://orcid.org/0000-0002-0356-7067 2017. Highly productive CO2 hydrogenation to methanol – a tandem catalytic approach via amide intermediates. Chemical Communications 53 (68) , pp. 9502-9504. 10.1039/C7CC04613H

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Abstract

A new system for CO2 reduction to methanol has been demonstrated using homogeneous ruthenium catalysts with a range of amine auxiliaries. Modification of this amine has a profound effect on the yield and selectivity of the reaction. A TON of 8900 and TOF of 4500 h−1 is achieved using a [RuCl2(Ph2PCH2CH2NHMe)2] catalyst with a diisopropylamine auxiliary.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	22 October 2018
Date of Acceptance:	23 June 2017
Last Modified:	28 Nov 2024 19:45
URI:	https://orca.cardiff.ac.uk/id/eprint/116083

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