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Cooperative Lewis pairs based on late transition metals: activation of small molecules by platinum(0) and B(C6F5)3

Forrest, Sebastian J. K., Clifton, Jamie, Fey, Natalie, Pringle, Paul G., Sparkes, Hazel A. and Wass, Duncan F. 2015. Cooperative Lewis pairs based on late transition metals: activation of small molecules by platinum(0) and B(C6F5)3. Angewandte Chemie International Edition 54 (7) , pp. 2223-2227. 10.1002/anie.201409872

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Abstract

A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: Wiley
ISSN: 1433-7851
Date of First Compliant Deposit: 25 October 2018
Date of Acceptance: 23 December 2014
Last Modified: 25 Nov 2020 09:46
URI: http://orca.cardiff.ac.uk/id/eprint/116193

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