Cooperative Lewis pairs based on late transition metals: activation of small molecules by platinum(0) and B(C6F5)3

Forrest, Sebastian J. K., Clifton, Jamie, Fey, Natalie, Pringle, Paul G., Sparkes, Hazel A. and Wass, Duncan F. ORCID: https://orcid.org/0000-0002-0356-7067 2015. Cooperative Lewis pairs based on late transition metals: activation of small molecules by platinum(0) and B(C6F5)3. Angewandte Chemie International Edition 54 (7) , pp. 2223-2227. 10.1002/anie.201409872

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Abstract

A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Wiley
ISSN:	1433-7851
Date of First Compliant Deposit:	25 October 2018
Date of Acceptance:	23 December 2014
Last Modified:	26 Nov 2024 18:05
URI:	https://orca.cardiff.ac.uk/id/eprint/116193

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