Shaw, Paul A., Phillips, Jessica M., Newman, Christopher P., Clarkson, Guy J. and Rourke, Jonathan P. ORCID: https://orcid.org/0000-0002-8961-1021 2015. Intramolecular transcyclometallation: the exchange of an aryl-Pt bond for an alkyl-Pt bond via an agostic intermediate. Chemical Communications 51 (39) , pp. 8365-8368. 10.1039/C5CC02355F |
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Official URL: http://dx.doi.org/10.1039/C5CC02355F
Abstract
Oxidation of a square-planar platinum complex leads to a five coordinate cationic intermediate that can be stabilized and trapped out via an agostic interaction with the alkyl chain of a ligand. Subsequent reaction of this species leads to the formation of an alkyl–Pt bond at the expense of an aryl–Pt bond: an intramolecular transcyclometallation.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
Date of First Compliant Deposit: | 16 January 2019 |
Date of Acceptance: | 10 April 2015 |
Last Modified: | 05 May 2023 12:55 |
URI: | https://orca.cardiff.ac.uk/id/eprint/118446 |
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