Intramolecular transcyclometallation: the exchange of an aryl-Pt bond for an alkyl-Pt bond via an agostic intermediate

Shaw, Paul A., Phillips, Jessica M., Newman, Christopher P., Clarkson, Guy J. and Rourke, Jonathan P. ORCID: https://orcid.org/0000-0002-8961-1021 2015. Intramolecular transcyclometallation: the exchange of an aryl-Pt bond for an alkyl-Pt bond via an agostic intermediate. Chemical Communications 51 (39) , pp. 8365-8368. 10.1039/C5CC02355F

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Abstract

Oxidation of a square-planar platinum complex leads to a five coordinate cationic intermediate that can be stabilized and trapped out via an agostic interaction with the alkyl chain of a ligand. Subsequent reaction of this species leads to the formation of an alkyl–Pt bond at the expense of an aryl–Pt bond: an intramolecular transcyclometallation.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	16 January 2019
Date of Acceptance:	10 April 2015
Last Modified:	05 May 2023 12:55
URI:	https://orca.cardiff.ac.uk/id/eprint/118446

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