Santos Hernandez, Alba, Lewis, Richard James, Malta, Grazia, Howe, Alexander, Morgan, David John ORCID: https://orcid.org/0000-0002-6571-5731, Hampton, Euan, Gaskin, Paul and Hutchings, Graham J. ORCID: https://orcid.org/0000-0001-8885-1560 2019. The direct synthesis of hydrogen peroxide over Au-Pd supported nanoparticles under ambient conditions. Industrial & Engineering Chemistry Research 58 (28) , pp. 12623-12631. 10.1021/acs.iecr.9b02211 |
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Abstract
The direct synthesis of hydrogen peroxide (H2O2) from molecular H2 and O2 over Au-Pd / TiO2 catalysts prepared using a modified impregnation methodology is studied. Initially we investigated the role of Au: Pd ratio on the catalytic activity towards H2O2 formation and its subsequent degradation under conditions that have previously been found to be optimal for the formation of H2O2 using high pressure reactants and low temperatures. Subsequently, we have conducted a detailed study of H2O2 synthesis under ambient conditions which are both more challenging for achieving high yields of H2O2 and are more likely to be used for future industrial applications.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry Cardiff Catalysis Institute (CCI) |
Publisher: | American Chemical Society |
ISSN: | 0888-5885 |
Funders: | Dwr Cymru Welsh Water |
Date of First Compliant Deposit: | 1 July 2019 |
Date of Acceptance: | 25 June 2019 |
Last Modified: | 05 Nov 2024 23:30 |
URI: | https://orca.cardiff.ac.uk/id/eprint/123851 |
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