Stabilisation of eudesmane cation by tryptophan 334 during aristolochene synthase catalysis

Deligeorgopoulou, Athina, Taylor, Susan E., Forcat, Silvia and Allemann, Rudolf Konrad ORCID: https://orcid.org/0000-0002-1323-8830 2003. Stabilisation of eudesmane cation by tryptophan 334 during aristolochene synthase catalysis. Chemical Communications (17) , pp. 2162-2163. 10.1039/b306867f

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Abstract

Analysis of the hydrocarbons produced during catalysis by mutants of aristolochene synthase from Penicillium roqueforti indicated that Trp 334 had a pivotal function for the efficient production of aristolochene from farnesylpyrophosphate most likely by stabilising the intermediate, eudesmane cation.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	1359-7345
Last Modified:	18 Oct 2022 13:19
URI:	https://orca.cardiff.ac.uk/id/eprint/13476

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