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Triplet-forming thionated donor-acceptor chromophores for electrochemically amphoteric photosensitization

Wright, Anna I., Kariuki, Benson M. and Wu, Yi-Lin 2021. Triplet-forming thionated donor-acceptor chromophores for electrochemically amphoteric photosensitization. European Journal of Organic Chemistry 2021 (33) , pp. 4647-4652. 10.1002/ejoc.202100793

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Abstract

Thiocarbonylation has been shown to be a promising tool for developing heavy-atom-free triplet photosensitizers from donor−acceptor chromophores. It was demonstrated that triplet-state formation from the thiocarbonyls is independent of the donor−acceptor interactions and that the thionated chromophores can be utilized as amphoteric photoredox catalysts that have comparable catalytic activities to common inorganic photosensitizers.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 1434-193X
Funders: EPSRC and Welsh Government
Date of First Compliant Deposit: 15 September 2021
Date of Acceptance: 5 August 2021
Last Modified: 20 Sep 2021 13:45
URI: http://orca.cardiff.ac.uk/id/eprint/144155

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