Triplet-forming thionated donor-acceptor chromophores for electrochemically amphoteric photosensitization

Wright, Anna I., Kariuki, Benson M. ORCID: https://orcid.org/0000-0002-8658-3897 and Wu, Yi-Lin ORCID: https://orcid.org/0000-0003-0253-1625 2021. Triplet-forming thionated donor-acceptor chromophores for electrochemically amphoteric photosensitization. European Journal of Organic Chemistry 2021 (33) , pp. 4647-4652. 10.1002/ejoc.202100793

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Abstract

Thiocarbonylation has been shown to be a promising tool for developing heavy-atom-free triplet photosensitizers from donor−acceptor chromophores. It was demonstrated that triplet-state formation from the thiocarbonyls is independent of the donor−acceptor interactions and that the thionated chromophores can be utilized as amphoteric photoredox catalysts that have comparable catalytic activities to common inorganic photosensitizers.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Advanced Research Computing @ Cardiff (ARCCA) Chemistry
Publisher:	Wiley
ISSN:	1434-193X
Funders:	EPSRC and Welsh Government
Date of First Compliant Deposit:	15 September 2021
Date of Acceptance:	5 August 2021
Last Modified:	02 Aug 2024 15:46
URI:	https://orca.cardiff.ac.uk/id/eprint/144155

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