Synthesis and Lewis acidity of fluorinated triaryl borates

Alharbi, Mashael, van Ingen, Yara, Roldan Martinez, Alberto ORCID: https://orcid.org/0000-0003-0353-9004, Kaehler, Tanja and Melen, Rebecca ORCID: https://orcid.org/0000-0003-3142-2831 2023. Synthesis and Lewis acidity of fluorinated triaryl borates. Dalton Transactions 52 (6) , pp. 1820-1825. 10.1039/D2DT04095F

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Abstract

A series of fluorinated triaryl borates B(OArF)3 (ArF = 2-FC6H4, 3-FC6H4, 4-FC6H4, 2,4-F2C6H3, 3,5-F2C6H3, 2,3,4-F3C6H2, 2,4,6-F3C6H2, 3,4,5-F3C6H2) have been prepared and isolated from the reactions of the mono-, di-, or tri-fluorophenol with BCl3. The Lewis acidity of these borates has been determined by NMR spectroscopic and theoretical methods and compared to their well-established borane counterpart.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Advanced Research Computing @ Cardiff (ARCCA) Cardiff Catalysis Institute (CCI) Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Funders:	EPSRC
Date of First Compliant Deposit:	19 January 2023
Date of Acceptance:	13 January 2023
Last Modified:	02 Aug 2024 08:39
URI:	https://orca.cardiff.ac.uk/id/eprint/156087

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