Alharbi, Mashael, van Ingen, Yara, Roldan Martinez, Alberto  ORCID: https://orcid.org/0000-0003-0353-9004, Kaehler, Tanja and Melen, Rebecca ORCID: https://orcid.org/0000-0003-3142-2831
2023.
Synthesis and Lewis acidity of fluorinated triaryl borates.
Dalton Transactions
52
(6)
, pp. 1820-1825.
10.1039/D2DT04095F
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Official URL: http://dx.doi.org/10.1039/D2DT04095F
Abstract
A series of fluorinated triaryl borates B(OArF)3 (ArF = 2-FC6H4, 3-FC6H4, 4-FC6H4, 2,4-F2C6H3, 3,5-F2C6H3, 2,3,4-F3C6H2, 2,4,6-F3C6H2, 3,4,5-F3C6H2) have been prepared and isolated from the reactions of the mono-, di-, or tri-fluorophenol with BCl3. The Lewis acidity of these borates has been determined by NMR spectroscopic and theoretical methods and compared to their well-established borane counterpart.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Professional Services > Advanced Research Computing @ Cardiff (ARCCA) Research Institutes & Centres > Cardiff Catalysis Institute (CCI) Schools > Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| Funders: | EPSRC |
| Date of First Compliant Deposit: | 19 January 2023 |
| Date of Acceptance: | 13 January 2023 |
| Last Modified: | 02 Aug 2024 08:39 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/156087 |
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