Hydrofunctionalization reactions of heterocumulenes: Formation of C–X (X = B, N, O, P, S and Si) bonds by homogeneous metal catalysts

Huke, Cameron and Kays, Deborah L. ORCID: https://orcid.org/0000-0002-4616-6001 2021. Hydrofunctionalization reactions of heterocumulenes: Formation of C–X (X = B, N, O, P, S and Si) bonds by homogeneous metal catalysts. Perez, Pedro J., ed. Advances in Organometallic Chemistry, Vol. 75. Elsevier, pp. 1-54. (10.1016/bs.adomc.2021.01.003)

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Abstract

The addition of E–H moieties to unsaturated bonds is an atom efficient way to synthesize heteroatom-containing molecules has dramatically increased in use. The majority of literature has focused on the addition of E–H moieties to alkene and alkyne substrates, with significantly less attention placed on the use of heteroatom-rich C = X bonds (X = O, S, N), and, in particular, the heterocumulenes (X = C = Y, X = O, S, NR and Y = NR) for this purpose. Herein, we will describe catalyzed and catalyst-free examples of the hydroboration (H–B(R)2), hydroamination (H–NR2), hydroalkoxylation (H–OR), hydrophosphination (H–PR2), hydrophosphinylation (H–P(O)R2), hydrophosphonylation (H–P(O)(OR)2), hydrothiolation (H–SR) and hydrosilylation (H–SiR3) of carbodiimides, isocyanates and isothiocyanates.

Item Type:	Book Section
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Elsevier
ISBN:	9780128245811
ISSN:	00653055
Last Modified:	22 Jul 2024 10:54
URI:	https://orca.cardiff.ac.uk/id/eprint/170294

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