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Self-assembly of a 3-D triply interlocked chiral [2] catenane

Westcott, Aleema, Fisher, Julie, Harding, Lindsay P., Rizkallah, Pierre and Hardie, Michaele J. 2008. Self-assembly of a 3-D triply interlocked chiral [2] catenane. Journal of the American Chemical Society 130 (10) , pp. 2950-2951. 10.1021/ja8002149

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A tripodal cyclotriveratrylene-based ligand with chelating 2,2‘-bipyridine arms self-assembles with either Zn(NO3)2 or Co(NO3)2 to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Medicine
Subjects: Q Science > QD Chemistry
Q Science > QH Natural history > QH301 Biology
Q Science > QH Natural history > QH426 Genetics
Publisher: American Chemical Society
ISSN: 0002-7863
Last Modified: 04 Jun 2017 03:59

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