Hammond, Ceri ORCID: https://orcid.org/0000-0002-9168-7674, Conrad, Sabrina and Hermans, Ive 2012. Simple and scalable preparation of highly active Lewis acidic Sn-beta. Angewandte Chemie - International Edition 51 (47) , pp. 11736-11739. 10.1002/anie.201206193 |
Official URL: http://dx.doi.org/10.1002/anie.201206193
Abstract
Tin goes in: The solid Lewis acid Sn-zeolite β is obtained in a simple and scalable procedure (see scheme). A high metal content can be obtained, without undesirable side-effects. The space-time-yields of the resulting catalysis are over one order-of-magnitude larger than those of the state-of-the-art materials for the Baeyer–Villiger oxidation of cyclohexanone and the synthesis of ethyl lactate from the triose dihydroxyacetone.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | Lewis acid catalysis; selective oxidation; sustainable chemistry; triose isomerization; zeolite synthesis |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Last Modified: | 25 Oct 2022 09:10 |
URI: | https://orca.cardiff.ac.uk/id/eprint/57536 |
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