Simple and scalable preparation of highly active Lewis acidic Sn-beta

Hammond, Ceri ORCID: https://orcid.org/0000-0002-9168-7674, Conrad, Sabrina and Hermans, Ive 2012. Simple and scalable preparation of highly active Lewis acidic Sn-beta. Angewandte Chemie - International Edition 51 (47) , pp. 11736-11739. 10.1002/anie.201206193

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Abstract

Tin goes in: The solid Lewis acid Sn-zeolite β is obtained in a simple and scalable procedure (see scheme). A high metal content can be obtained, without undesirable side-effects. The space-time-yields of the resulting catalysis are over one order-of-magnitude larger than those of the state-of-the-art materials for the Baeyer–Villiger oxidation of cyclohexanone and the synthesis of ethyl lactate from the triose dihydroxyacetone.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Lewis acid catalysis; selective oxidation; sustainable chemistry; triose isomerization; zeolite synthesis
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Last Modified:	25 Oct 2022 09:10
URI:	https://orca.cardiff.ac.uk/id/eprint/57536

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