Garcia Canadas, Jorge and Gao, Min ORCID: https://orcid.org/0000-0001-9591-5825 2014. Low frequency impedance spectroscopy analysis of thermoelectric modules. Journal of Electronic Materials 43 (6) , pp. 2411-2414. 10.1007/s11664-014-3095-4 |
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Abstract
Impedance spectroscopy is a well-established technique for the study of semiconductors and energy-related devices. However, in the area of thermoelectrics (TEs), this technique is not frequently used and there is a lack of a physical background for a proper interpretation of the results. Usually, in the low frequency regime, the impedance spectrum of TE modules working in cooling mode is characterized by a semicircle which can be modelled as a parallel connection of a resistor and a capacitor. Here, we present a theoretical analysis to understand the origin of both parameters in bulk TE modules working as Peltier coolers. The analysis introduces a thermoelectric capacitance and a thermoelectric resistance that are defined by the temperature, the Seebeck coefficient and the thermal properties of the module (specific heat and thermal conductivity, respectively). The product of both provides a time constant that directly relates to the thermal diffusivity. Our analysis provides a theoretical model able to interpret the low frequency results and obtain relevant thermal parameters from a single impedance measurement.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Engineering |
Subjects: | T Technology > TA Engineering (General). Civil engineering (General) T Technology > TK Electrical engineering. Electronics Nuclear engineering |
Uncontrolled Keywords: | Characterisation of thermoelectric modules; ac electrical impedance; thermal constants |
Additional Information: | Online publication date: March 2014. Post-print self-archived in accordance with publisher's policy at http://www.sherpa.ac.uk/romeo/issn/0361-5235/ (last accessed 25 April 2014). |
Publisher: | Springer |
ISSN: | 0361-5235 |
Date of First Compliant Deposit: | 30 March 2016 |
Last Modified: | 08 May 2023 06:40 |
URI: | https://orca.cardiff.ac.uk/id/eprint/59194 |
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