Adams, Steffan, Dirr, Nicolas P. ORCID: https://orcid.org/0000-0003-3634-7367, Peletier, Mark and Zimmer, Johannes
2013.
Large deviations and gradient flows.
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
371
(2005)
, 20120341.
10.1098/rsta.2012.0341
|
Abstract
In recent work we uncovered intriguing connections between Otto’s characterization of diffusion as an entropic gradient flow on the one hand and large-deviation principles describing the microscopic picture (Brownian motion) on the other. In this paper, we sketch this connection, show how it generalizes to a wider class of systems and comment on consequences and implications. Specifically, we connect macroscopic gradient flows with large-deviation principles, and point out the potential of a bigger picture emerging: we indicate that, in some non-equilibrium situations, entropies and thermodynamic free energies can be derived via large-deviation principles. The approach advocated here is different from the established hydrodynamic limit passage but extends a link that is well known in the equilibrium situation.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Mathematics |
| Subjects: | Q Science > QA Mathematics |
| Publisher: | The Royal Society |
| ISSN: | 1364-503X |
| Last Modified: | 27 Oct 2022 09:41 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/67303 |
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