Uehlin, Lars and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667
2001.
Mixed acetals as new precursors for selenium electrophiles.
Phosphorus, Sulfur and Silicon and the Related Elements
171
(1)
, pp. 189-194.
10.1080/10426500108046650
|
Abstract
A wide range of precursors for selenium electrophiles is already known, but the requirements for the development of polymer-bound selenium reagents are different. Herein we report mixed acetals as new precursor molecules for the synthesis of selenium electophiles under very mild reaction conditions. The use of (MeOCH2Se)2 allows a very fast access to these mixed acetals. Chiral precursor molecules can be synthesized as well and employed in efficient stereoselective selenenylation reactions.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Uncontrolled Keywords: | selenium electrophiles, mixed acetals, stereoselective synthesis |
| Publisher: | Taylor & Francis |
| ISSN: | 1042-6507 |
| Last Modified: | 18 Oct 2022 12:25 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/9761 |
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