Uehlin, Lars and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2001. Mixed acetals as new precursors for selenium electrophiles. Phosphorus, Sulfur and Silicon and the Related Elements 171 (1) , pp. 189-194. 10.1080/10426500108046650 |
Abstract
A wide range of precursors for selenium electrophiles is already known, but the requirements for the development of polymer-bound selenium reagents are different. Herein we report mixed acetals as new precursor molecules for the synthesis of selenium electophiles under very mild reaction conditions. The use of (MeOCH2Se)2 allows a very fast access to these mixed acetals. Chiral precursor molecules can be synthesized as well and employed in efficient stereoselective selenenylation reactions.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | selenium electrophiles, mixed acetals, stereoselective synthesis |
Publisher: | Taylor & Francis |
ISSN: | 1042-6507 |
Last Modified: | 18 Oct 2022 12:25 |
URI: | https://orca.cardiff.ac.uk/id/eprint/9761 |
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