Mixed acetals as new precursors for selenium electrophiles

Uehlin, Lars and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2001. Mixed acetals as new precursors for selenium electrophiles. Phosphorus, Sulfur and Silicon and the Related Elements 171 (1) , pp. 189-194. 10.1080/10426500108046650

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Abstract

A wide range of precursors for selenium electrophiles is already known, but the requirements for the development of polymer-bound selenium reagents are different. Herein we report mixed acetals as new precursor molecules for the synthesis of selenium electophiles under very mild reaction conditions. The use of (MeOCH2Se)2 allows a very fast access to these mixed acetals. Chiral precursor molecules can be synthesized as well and employed in efficient stereoselective selenenylation reactions.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	selenium electrophiles, mixed acetals, stereoselective synthesis
Publisher:	Taylor & Francis
ISSN:	1042-6507
Last Modified:	18 Oct 2022 12:25
URI:	https://orca.cardiff.ac.uk/id/eprint/9761

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