Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction

Celorrio, V., Morris, Louis J., Cattelan, M., Fox, N.A. and Fermin, D.J. 2017. Tellurium-doped lanthanum manganite as catalysts for the oxygen reduction reaction. MRS Communications 7 (2) , pp. 193-198. 10.1557/mrc.2017.22

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Abstract

The effect of tellurium (Te) doping on the electrocatalytic activity of La1−xTexMnO3 toward the oxygen reduction reaction is investigated for the first time. La1−xTexMnO3 with x-values up 23% were synthesized from a single ionic liquid-based precursor, yielding nanoparticles with mean diameter in the range of 40–68 nm and rhombohedral unit cell. Electrochemical studies were performed on carbon-supported particles in alkaline environment. The composition dependence activity is discussed in terms of surface density of Mn sites and changes in the effective Mn oxidation state.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Research Institutes & Centres > Cardiff Catalysis Institute (CCI) Schools > Chemistry
Publisher:	Cambridge University Press
ISSN:	2159-6859
Funders:	EPSRC
Date of First Compliant Deposit:	11 May 2017
Date of Acceptance:	23 March 2017
Last Modified:	13 Nov 2024 18:30
URI:	https://orca.cardiff.ac.uk/id/eprint/100521

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