Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Understanding the role of designed solid acid sites in the low-temperature production of ϵ-Caprolactam

Potter, Matthew E., Chapman, Stephanie, O'Malley, Alexander, Levy, Alan, Carravetta, Marina, Mezza, Thomas M., Parker, Stewart F. and Raja, Robert 2017. Understanding the role of designed solid acid sites in the low-temperature production of ϵ-Caprolactam. ChemCatChem 9 (11) , pp. 1897-1900. 10.1002/cctc.201700516

[thumbnail of POST PRINT Potter_et_al-2017-ChemCatChem.pdf]
Preview
PDF - Accepted Post-Print Version
Download (418kB) | Preview

Abstract

Modern society is placing increasing demands on commodity chemicals, driven by the ever-growing global population and the desire for improved standards of living. As the polymer industry grows, a sustainable route to ϵ-caprolactam, the precursor to the recyclable nylon-6 polymer, is becoming increasingly important. To this end, we have designed and characterized a recyclable SAPO catalyst using a range of characterization techniques, to achieve near quantitative yields of ϵ-caprolactam from cyclohexanone oxime. The catalytic process operates under significantly less energetically demanding conditions than other widely practiced industrial processes.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: beckmann rearrangement; aluminophosphates; heterogeneous catalysis; solid acid; sustainable chemistry
Publisher: Wiley
ISSN: 1867-3880
Funders: EPSRC
Date of First Compliant Deposit: 21 June 2017
Date of Acceptance: 4 April 2017
Last Modified: 06 Nov 2023 21:18
URI: https://orca.cardiff.ac.uk/id/eprint/101636

Citation Data

Cited 15 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics