Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols

Robinson, M. C. W., Davies, A. M., Mabbet, I., Davies, T. E., Apperley, D. C., Taylor, S. H. ORCID: https://orcid.org/0000-0002-1933-4874 and Graham, A. E. 2010. Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols. Journal of Molecular Catalysis A: Chemical 329 (1-2) , pp. 57-63. 10.1016/j.molcata.2010.06.018

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Abstract

The ability of nanoporous aluminosilicate materials, synthesized using an evaporation-induced self-assembly (EISA) approach, to function as catalysts for the formation of β-amino alcohols from aromatic amines and epoxides was assessed. Materials containing high aluminium loadings displayed catalytic activity, giving the desired β-amino alcohols in high yield and with high selectivity for the Markovnikov addition product. These materials exhibited nanoporous pores, typically 1.34-1.49 nm, with a narrow pore size distribution and the expected large surface areas. © 2010 Elsevier B.V.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI) Research Institutes & Centres > Neuroscience and Mental Health Research Institute (NMHII)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Addition products; Aluminosilicate materials; Amino alcohols; Aromatic amines; Catalytic activity; Evaporation-induced self-assembly; Heterogeneous catalyst; High selectivity; High yield; Large surface area; Lewis acid catalysts; Nano-porous; Narrow pores, Acids; Alcohols; Aluminosilicates; Amination; Catalysts; Evaporation; Pore size; Self assembly, Amines
Additional Information:	cited By (since 1996) 3
Publisher:	Elsevier BV
ISSN:	13811169
Last Modified:	14 Nov 2024 08:41
URI:	https://orca.cardiff.ac.uk/id/eprint/10233

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