A study of the methane-deuterium exchange reaction over a range of metal oxides

Hargreaves, J. S. J., Hutchings, Graham John ORCID: https://orcid.org/0000-0001-8885-1560, Joyner, R. W. and Taylor, Stuart H. ORCID: https://orcid.org/0000-0002-1933-4874 2002. A study of the methane-deuterium exchange reaction over a range of metal oxides. Applied Catalysis A: General 227 (1-2) , pp. 191-200. 10.1016/S0926-860X(01)00935-8

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Abstract

Methane-deuterium exchange reaction was analyzed for a range of metal oxides. The metal oxides were evaluated for their ability to activate methane/deuterium exchange as a probe reaction. Ga2O3 was found to be the most active material followed by ZnO. Results indicated the possible contribution of oxide basicity in the activation of methane.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Catalyst activity; Chemical activation; Chemical bonds; Dehydrogenation; Deuterium; Dissociation; Ion exchange; Reduction, Metal oxides, Reaction kinetics
Additional Information:	cited by (since 1996) 12
Publisher:	Elsevier BV
ISSN:	0926860X
Last Modified:	05 Jan 2023 14:20
URI:	https://orca.cardiff.ac.uk/id/eprint/10299

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