Biot, Nicolas and Bonifazi, Davide  ORCID: https://orcid.org/0000-0001-5717-0121
2018.
Programming recognition arrays through double chalcogen-bonding interactions.
Chemistry - a European Journal
24
(21)
, pp. 5439-5443.
10.1002/chem.201705428
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Abstract
In this work, we have programmed and synthesized a recognition motif constructed around a chalcogenazolo-pyridine scaffold (CGP) that, through the formation of frontal double chalcogen-bonding interactions, associates into dimeric EX-type complexes. The reliability of the double chalcogen-bonding interaction has been shown at the solid-state by X-ray analysis, depicting the strongest recognition persistence for a Te-congener. The high recognition fidelity, chemical and thermal stability and easy derivatization at the 2-position makes CGP a convenient motif for constructing supramolecular architectures through programmed chalcogen-bonding interactions.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Publisher: | WileyBlackwell |
| ISSN: | 0947-6539 |
| Date of First Compliant Deposit: | 7 December 2017 |
| Date of Acceptance: | 30 November 2017 |
| Last Modified: | 12 Nov 2024 17:15 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/107406 |
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