Sciutto, Andrea, Berezin, Andrey, Lo Cicero, Matteo, Miletic, Tanja, Stopin, Antoine and Bonifazi, Davide ![]() |
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Abstract
The tailored synthesis of homo (A2) and hetero (AB) N-substituted peri-xanthenoxanthene diimides (PXXDIs) and peri-functionalized PXX monoimides (PXXMIs) from 3-hydroxy naphthalic anhydride is described. As A2-type PXXDIs could be synthesized in one step, AB-type PXXDIs and PXXMIs were prepared through a modular approach capitalizing on sequential Suzuki coupling, imidation, and Pummerer reactions with very high yields. In view of their potential applications as organic semiconductors, self-organization studies were performed through liquid deposition on surfaces, depicting the formation of islands, needles, and rods.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | American Chemical Society |
ISSN: | 0022-3263 |
Funders: | MSCA-ITN ETN network �PHOTOTRAIN�, the MSCA-RISE project �INFUSION� |
Date of First Compliant Deposit: | 13 November 2018 |
Date of Acceptance: | 26 October 2018 |
Last Modified: | 05 Nov 2024 17:15 |
URI: | https://orca.cardiff.ac.uk/id/eprint/116697 |
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