Applications of electron paramagnetic resonance spectroscopy for interrogating catalytic systems

Spencer, Jacob, Folli, Andrea ORCID: https://orcid.org/0000-0001-8913-6606, Richards, Emma ORCID: https://orcid.org/0000-0001-6691-2377 and Murphy, Damien M. ORCID: https://orcid.org/0000-0002-5941-4879 2018. Applications of electron paramagnetic resonance spectroscopy for interrogating catalytic systems. Chechik, Victor and Murphy, Damien M, eds. Electron Paramagnetic Resonance, Vol. 26. Royal Society of Chemistry, pp. 130-170. (10.1039/9781788013888-00130)

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Abstract

Species bearing unpaired electrons, including paramagnetic redox metal centres, surface defect centres, reactive oxygen species, adsorbed radical anions, are often involved in catalytic reactions. These species can be readily and thoroughly interrogated using Electron Paramagnetic Resonance (EPR) spectroscopy, providing information on the identity, chemical composition and even the dynamics of the centres themselves, thereby helping to elucidate the involvement of the radicals in the reaction cycles. This review will summarise and highlight the applications of EPR in heterogeneous, homogeneous, photocatalytic and microporous materials, all of which are of vital importance to the field of catalysis.

Item Type:	Book Section
Date Type:	Published Online
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISBN:	978-1-78801-372-7
ISSN:	1465-1955
Last Modified:	16 Oct 2024 10:17
URI:	https://orca.cardiff.ac.uk/id/eprint/118185

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