Palladium(II)-catalyzed C-H bond arylation of electron-deficient arenes at room temperature

Tredwell, Matthew J. ORCID: https://orcid.org/0000-0002-4184-5611, Gulias, Moises, Gaunt Bremeyer, Nadine, Johansson, Carin C C, Collins, Beatrice S L and Gaunt, Matthew J 2010. Palladium(II)-catalyzed C-H bond arylation of electron-deficient arenes at room temperature. Angewandte Chemie International Edition 50 (5) , pp. 1076-1079. 10.1002/anie.201005990

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Abstract

Mild and tolerant: A novel PdII‐catalyzed CH bond arylation with aryl‐BF3K salts transforms various electron‐deficient arenes under mild reaction conditions. Benzaldehydes are functionalized in the ortho position using a temporary imine directing group that controls the cyclopalladation. A broad range of benzaldimines are compatible with this process.

Item Type:	Article
Status:	Published
Schools:	Medicine
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	04 Nov 2022 12:12
URI:	https://orca.cardiff.ac.uk/id/eprint/122228

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